The Hollywood beauty is dressed by celebrity stylist Rachel Zoe, and the fashion expert says the gorgeous actress is a joy to work with.
Thanks to her star-studded client list, Rachel has 'too many' favourite red carpet moment to name, but says Anne’s Golden Globe look last year stands out.
'I think Anne Hathaway has had a few winners,' she told People.
'Her Armani Privé last year for the Globes is one of my favourites because it was super-glamorous in a very kind of vintage Hollywood way, but also extremely modern, and I loved that.'
Rachel also dressed Anne in an impressive seven gowns for the 2011 Academy Awards.
The stylist’s A-list client list doesn’t stop at Anne.
She also dresses the likes of Cameron Diaz and Kate Hudson, who she believes also have had 'too many great moments to name'.
The fashionista has joked she is probably inclined to say that anyway.
'I’m biased toward my clients,' she laughed.